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Diethylaluminium cyanide
・ Diethylamine
・ Diethylamino hydroxybenzoyl hexyl benzoate
・ Diethylaminoethyl cellulose
・ Diethylaminosulfur trifluoride
・ Diethylaniline
・ Diethylcarbamazine
・ Diethylene glycol
・ Diethylene glycol diethyl ether
・ Diethylene glycol dinitrate
・ Diethylenetriamine
・ Diethylethanolamine
・ Diethylhydroxylamine
・ Diethylmercury
・ Diethylpyrocarbonate


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Diethylaluminium cyanide : ウィキペディア英語版
Diethylaluminium cyanide

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Diethylaluminum cyanide ("Nagata's reagent") is the organoaluminum compound with formula ((C2H5)2AlCN)n. This colorless compound is usually handled as a solution in toluene. It is a reagent for the hydrocyanation of α,β-unsaturated ketones.〔(【引用サイトリンク】MSDS - 276863 )〕〔
== Synthesis ==
Diethylaluminum cyanide was originally generated by treatment of triethylaluminum with a slight excess of hydrogen cyanide. The product is typically stored in ampoules because it is highly toxic. It dissolves in toluene, benzene, hexane and isopropyl ether. It undergoes hydrolysis readily and is not compatible with protic solvents.
:Et3Al + HCN → 1/n (Et2AlCN)n + EtH

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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